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Abstract Nitrous oxide (N 2 O) is important to the global radiative budget of the atmosphere and contributes to the depletion of stratospheric ozone. Globally the ocean represents a large net flux of N 2 O to the atmosphere but the direction of this flux varies regionally. Our understanding of N 2 O production and consumption processes in the ocean remains incomplete. Traditional understanding tells us that anaerobic denitrification, the reduction of NO 3 − to N 2 with N 2 O as an intermediate step, is the sole biological means of reducing N 2 O, a process known to occur in anoxic environments only. Here we present experimental evidence of N 2 O removal under fully oxygenated conditions, coupled with observations of bacterial communities with novel, atypical gene sequences for N 2 O reduction. The focus of this work was on the high latitude Atlantic Ocean where we show bacterial consumption sufficient to account for oceanic N 2 O depletion and the occurrence of regional sinks for atmospheric N 2 O. 

This paper proposes a simple and fast technique for power device open circuit (OC) fault detection in stacked multicell converters (SMCs). A mitigation technique allowing for fault-tolerant operation using a simple front-end routing circuit is also proposed for SMCs. The fault detection concept only needs to sense the voltage and direction of current at the output terminal of the SMC to detect and localize an OC switch fault to a particular rail of the SMC. The proposed technique compares the measured and expected voltage levels considering the commanded switch states and the direction of the terminal current flow. Once an OC fault is detected and localized, the front-end routing circuit will be activated to reconfigure the SMC converter to a simple flying capacitor multilevel converter (FCMC) to maintain the output power flow with a reduced number of voltage levels. A window detector circuit is proposed to track the output voltage level and current direction with high bandwidth. Simulations were performed to validate the fault detection method and router performance. The functionality of windows detector is investigated with a hardware prototype 7 level 300 V SMC. 

Abstract. Large-scale climatic forcing is impactingoceanic biogeochemical cycles and is expected to influence the water-columndistribution of trace gases, including methane and nitrous oxide. Our abilityas a scientific community to evaluate changes in the water-column inventoriesof methane and nitrous oxide depends largely on our capacity to obtain robustand accurate concentration measurements that can be validated acrossdifferent laboratory groups. This study represents the first formalinternational intercomparison of oceanic methane and nitrous oxidemeasurements whereby participating laboratories received batches of seawatersamples from the subtropical Pacific Ocean and the Baltic Sea. Additionally,compressed gas standards from the same calibration scale were distributed tothe majority of participating laboratories to improve the analytical accuracyof the gas measurements. The computations used by each laboratory to derivethe dissolved gas concentrations were also evaluated for inconsistencies(e.g., pressure and temperature corrections, solubility constants). Theresults from the intercomparison and intercalibration provided invaluableinsights into methane and nitrous oxide measurements. It was observed thatanalyses of seawater samples with the lowest concentrations of methane andnitrous oxide had the lowest precisions. In comparison, while the analyticalprecision for samples with the highest concentrations of trace gases wasbetter, the variability between the different laboratories was higher:36% for methane and 27% for nitrous oxide. In addition, thecomparison of different batches of seawater samples with methane and nitrousoxide concentrations that ranged over an order of magnitude revealed theramifications of different calibration procedures for each trace gas.Finally, this study builds upon the intercomparison results to developrecommendations for improving oceanic methane and nitrous oxide measurements,with the aim of precluding future analytical discrepancies betweenlaboratories.